Saturday 22 October 1966 at Molineux (Att 21,199)

Wolves (0) 2 (Woodfield 63, Hunt 85): Davies, J Wilson, Thomson, Bailey, Woodfield, Flowers, Wharton, Hunt, McIlmoyle, Burnside, Wagstaffe; Sub Hawkins.
Plymouth Argyle (0) 1 (Piper 87): Shearing, Rounsevell, Baird, Piper, Nelson, Newman, Jones, Bloomfield, Bickle, Reynolds, Jennings; Sub Davey.

Referee: Mr J Cattlin (Rochdale).
Order of Goals: W,W,p.
Position: 5th.