| First Team Matches | Associated with both clubs |
| Seasons | Competitions | Date | Venue | Results | Wolves Manager | Villarreal Manager | Referee | |
| 2018/19 | Friendly | 4 August 2018 | Molineux | W | 2-1 | Nuno Espirito Santo | x | |
| 2022/23* | Friendly | 24 July 2022 | Alicante | L | 1-2 | Bruna Lage | x |
* Match against Villarreal ‘B’ team.
