| Seasons | Competitions | Date | Venue | | Results | Wolves Manager | Liverpool Manager | Referee |
| 1894/95 | Football League (1) | 29 September 1894 | Molineux | W | 3-1 | Jack Addenbrooke | John McKenna | J Fox (Sheffield) |
| 1894/95 | Football League (1) | 1 December 1894 | Anfield Road | D | 3-3 | Jack Addenbrooke | John McKenna | A Pennington (Burslem) |
| 1895/96 | FA Cup | 15 February 1896 | Molineux | W | 2-0 | Jack Addenbrooke | John McKenna | A Kingscott (Derby) |
| 1896/97 | Football League (1) | 9 January 1897 | Molineux | L | 1-2 | Jack Addenbrooke | Tom Watson | J Cowley (Sheffield) |
| 1896/97 | Football League (1) | 4 March 1897 | Anfield Road | L | 0-3 | Jack Addenbrooke | Tom Watson | J Jeffries (Rotherham) |
| 1897/98 | Football League (1) | 20 November 1897 | Anfield Road | L | 0-1 | Jack Addenbrooke | Tom Watson | J Strawson (Lincoln) |
| 1897/98 | Football League (1) | 11 December 1897 | Molineux | W | 2-1 | Jack Addenbrooke | Tom Watson | W Jones (Leicester) |
| 1898/99 | Football League (1) | 17 September 1898 | Anfield Road | L | 0-1 | Jack Addenbrooke | Tom Watson | Unknown |
| 1898/99 | Football League (1) | 14 January 1899 | Molineux | D | 0-0 | Jack Addenbrooke | Tom Watson | J Stott (Rawtenstall) |
| 1899/00 | Football League (1) | 25 November 1899 | Anfield Road | D | 1-1 | Jack Addenbrooke | Tom Watson | J Lewis (Blackburn) |
| 1899/00 | Football League (1) | 31 March 1900 | Molineux | L | 0-1 | Jack Addenbrooke | Tom Watson | Unknown |
| 1900/01 | Football League (1) | 3 November 1900 | Molineux | W | 2-1 | Jack Addenbrooke | Tom Watson | J Fox (Sheffield) |
| 1900/01 | Football League (1) | 9 March 1901 | Anfield Road | L | 0-1 | Jack Addenbrooke | Tom Watson | J Ditchfield (Burslem) |
| 1901/02 | Football League (1) | 9 November 1901 | Anfield Road | L | 1-4 | Jack Addenbrooke | Tom Watson | AJ Barker (Hanley) |
| 1901/02 | Friendly | 18 November 1901 | Molineux | L | 1-2 | Jack Addenbrooke | Tom Watson | x |
| 1901/02 | Football League (1) | 8 March 1902 | Molineux | W | 3-1 | Jack Addenbrooke | Tom Watson | AJ Barker (Hanley) |
| 1902/03 | Football League (1) | 15 November 1902 | Anfield Road | L | 1-4 | Jack Addenbrooke | Tom Watson | D Hammond (Heywood) |
| 1902/03 | Football League (1) | 14 March 1903 | Molineux | | 0-2 A | Jack Addenbrooke | Tom Watson | Unknown |
| 1902/03 | Football League (1) | 27 April 1903 | Molineux | L | 0-2 | Jack Addenbrooke | Tom Watson | D Hammond (Heywood) |
| 1903/04 | Football League (1) | 12 December 1903 | Anfield Road | W | 2-1 | Jack Addenbrooke | Tom Watson | W Gilgryst (Manchester) |
| 1903/04 | Football League (1) | 28 December 1903 | Molineux | W | 4-2 | Jack Addenbrooke | Tom Watson | W Gilgryst (Manchester) |
| 1905/06 | Football League (1) | 9 December 1905 | Anfield Road | L | 0-4 | Jack Addenbrooke | Tom Watson | T Armitt (Leek) |
| 1905/06 | Football League (1) | 14 April 1906 | Molineux | L | 0-2 | Jack Addenbrooke | Tom Watson | T Armitt (Leek) |
| 1922/23 | FA Cup | 3 February 1923 | Molineux | L | 0-2 | George Jobey | ? | W Nunnerley (Wrexham) |
| 1932/33 | Football League (1) | 27 August 1932 | Anfield Road | L | 1-5 | Major Frank Buckley | George Patterson | H Cartlidge (Burslem) |
| 1932/33 | Football League (1) | 31 December 1932 | Molineux | W | 3-1 | Major Frank Buckley | George Patterson | H Cartlidge (Burslem) |
| 1933/34 | Football League (1) | 26 August 1933 | Molineux | W | 3-2 | Major Frank Buckley | George Patterson | E Wood (Sheffield) |
| 1933/34 | Football League (1) | 30 December 1933 | Anfield Road | D | 1-1 | Major Frank Buckley | George Patterson | E Wood (Sheffield) |
| 1934/35 | Football League (1) | 3 November 1934 | Anfield Road | L | 1-2 | Major Frank Buckley | George Patterson | W Lewington (Chelsea) |
| 1934/35 | Football League (1) | 16 March 1935 | Molineux | W | 5-3 | Major Frank Buckley | George Patterson | W Lewington (Chelsea) |
| 1935/36 | Football League (1) | 16 November 1935 | Molineux | W | 3-1 | Major Frank Buckley | George Patterson | G Jones (Nottingham) |
| 1935/36 | Football League (1) | 21 March 1936 | Anfield Road | W | 2-0 | Major Frank Buckley | George Patterson | G Jones (Nottingham) |
| 1936/37 | Football League (1) | 5 December 1936 | Molineux | W | 2-0 | Major Frank Buckley | George Kay | H McBride (Crewe) |
| 1936/37 | Football League (1) | 10 April 1937 | Anfield Road | L | 0-1 | Major Frank Buckley | George Kay | H McBride (Crewe) |
| 1937/38 | Football League (1) | 16 October 1937 | Molineux | W | 2-0 | Major Frank Buckley | George Kay | A Clark (Southgate) |
| 1937/38 | Football League (1) | 26 February 1938 | Anfield Road | W | 1-0 | Major Frank Buckley | George Kay | A Clark (Southgate) |
| 1938/39 | Football League (1) | 22 October 1938 | Molineux | D | 2-2 | Major Frank Buckley | George Kay | S Boardman (Hale) |
| 1938/39 | FA Cup | 11 February 1939 | Molineux | W | 4-1 | Major Frank Buckley | George Kay | R Blake (Middlesbrough) |
| 1938/39 | Football League (1) | 25 February 1939 | Anfield Road | W | 2-0 | Major Frank Buckley | George Kay | S Boardman (Hale) |
| 1946/47 | Football League (1) | 7 December 1946 | Anfield Road | W | 5-1 | Ted Vizard | George Kay | J Briggs (Cheadle) |
| 1946/47 | Football League (1) | 31 May 1947 | Molineux | L | 1-2 | Ted Vizard | George Kay | J Briggs (Cheadle) |
| 1947/48 | Football League (1) | 13 December 1947 | Anfield Road | L | 1-2 | Ted Vizard | George Kay | C Fletcher (Davenham, Cheshire) |
| 1947/48 | Football League (1) | 1 May 1948 | Molineux | L | 1-2 | Ted Vizard | George Kay | C Fletcher (Davenham, Cheshire) |
| 1948/49 | Football League (1) | 4 September 1948 | Molineux | D | 0-0 | Stan Cullis | George Kay | C Womersley (Davenport, Ches) |
| 1948/49 | FA Cup | 12 February 1949 | Molineux | W | 3-1 | Stan Cullis | George Kay | C Fletcher (Davenham, Cheshire) |
| 1948/49 | Football League (1) | 6 April 1949 | Anfield Road | D | 0-0 | Stan Cullis | George Kay | C Womersley (Davenport, Ches) |
| 1949/50 | Football League (1) | 26 November 1949 | Molineux | D | 1-1 | Stan Cullis | George Kay | A Bond (Fulham) |
| 1949/50 | Football League (1) | 18 March 1950 | Anfield Road | W | 2-0 | Stan Cullis | George Kay | A Bond (Fulham) |
| 1950/51 | Football League (1) | 19 August 1950 | Molineux | W | 2-0 | Stan Cullis | George Kay | B Flanagan (Sheffield) |
| 1950/51 | Football League (1) | 16 December 1950 | Anfield Road | W | 4-1 | Stan Cullis | George Kay | B Flanagan (Sheffield) |
