| 1952/53 | (2) | Wellington Town | Away | W | 5-0 |
| (3) | West Bromwich Albion | Home | W | 2-0 | |
| (4) | Birmingham City | Away | W | 5-0 | |
| (5) | Doncaster Rovers | Home | W | 6-0 | |
| (SF/1) | Huntley & Palmer | Home | W | 5-0 | |
| (SF/2) | Huntley & Palmer | Away | W | 6-0 | |
| (F/1) | Manchester United | Away | L | 1-7 | |
| (F/2) | Manchester United | Home | D | 2-2 |
| 1953/54 | (1) | Stoke City | Home | W | 7-0 |
| (2) | Derby County | Home | W | 8-0 | |
| (3) | Spalding | Home | W | 11-0 | |
| (4) | Nottingham Forest | Away | W | 1-0 | |
| (5) | Portsmouth | Away | W | 2-0 | |
| (SF/1) | West Ham United | Home | W | 6-1 | |
| (SF/2) | West Ham United | Away | W | 2-1 | |
| (F/1) | Manchester United | Home | D | 4-4 | |
| (F/2) | Manchester United | Away | L | 0-1 |
| 1954/55 | (1) | Port Vale | Home | W | 4-0 |
| (2) | Walsall | Home | W | 10-0 | |
| (3) | West Bromwich Albion | Away | L | 1-4 |
| 1955/56 | (1) | West Bromwich Albion | Home | W | 6-0 |
| (2) | Stoke City | Away | W | 3-2 | |
| (3) | Coventry City | Home | W | 3-1 | |
| (4) | Peterborough United | Home | W | 9-0 | |
| (5) | Bolton Wanderers | Away | L | 0-2 |
| 1956/57 | (1) | Luton Town | Away | L | 1-3 |
| 1957/58 | (1) | West Bromwich Albion | Away | D | 2-2 |
| (R) | West Bromwich Albion | Home | W | 6-1 | |
| (3) | Aston Villa | Away | W | 3-0 | |
| (3) | Stoke City | Home | D | 1-1 | |
| (R) | Stoke City | Away | W | 3-2 | |
| (4) | Leicester City | Home | W | 9-0 | |
| (5) | Bolton Wanderers | Home | D | 1-1 | |
| (R) | Bolton Wanderers | Away | W | 3-1 | |
| (SF/1) | Manchester United | Away | D | 1-1 | |
| (SF/2) | Manchester United | Home | W | 3-1 | |
| (F/1) | Chelsea | Away | L | 1-5 | |
| (F/2) | Chelsea | Home | W | 6-1 |
| 1958/59 | (2) | Stoke City | Home | W | 3-0 |
| (3) | West Bromwich Albion | Away | D | 1-1 | |
| (R) | West Bromwich Albion | Home | W | 4-2 | |
| (4) | Scunthorpe United | Away | W | 4-2 | |
| (5) | Manchester United | Away | L | 0-3 |
| 1959/60 | (1) | Peterborough United | Home | W | 5-0 |
| (2) | Walsall | Away | W | 7-1 | |
| (3) | Aston Villa | Away | L | 1-5 |
| 1960/61 | (1) | Corby Town | Away | W | 8-1 |
| (2) | Stoke City | Away | L | 0-5 |
| 1961/62 | (1) | Birmingham City | Away | W | 1-0 |
| (2) | Northampton Town | Away | W | 3-1 | |
| (3) | Stoke City | Home | W | 4-0 | |
| (4) | Sheffield United | Home | W | 3-0 | |
| (5) | Aston Villa | Away | W | 4-1 | |
| (SF/1) | Chelsea | Away | W | 1-0 | |
| (SF/2) | Chelsea | Home | W | 3-0 | |
| (F/1) | Newcastle United | Home | D | 1-1 | |
| (F/2) | Newcastle United | Away | L | 0-1 |
| 1962/63 | (2) | Leicester City | Away | W | 5-2 |
| (3) | Norwich City | Home | W | 2-0 | |
| (4) | Chelsea | Away | W | 1-0 | |
| (5) | Arsenal | Home | D | 1-1 | |
| (R) | Arsenal | Away | W | 4-0 | |
| (SF/1) | West Ham United | Home | D | 2-2 | |
| (SF/2) | West Ham United | Away | L | 2-4 |
| 1963/64 | (2) | Thornley Wood Athletic | Home | W | 3-1 |
| (3) | Aston Villa | Home | W | 1-0 | |
| (4) | Birmingham City | Home | W | 6-1 | |
| (5) | Manchester United | Away | L | 2-3 |
| 1964/65 | (2) | Walsall | Home | W | 5-0 |
| (3) | West Bromwich Albion | Away | D | 1-1 | |
| (R) | West Bromwich Albion | Home | W | 2-0 | |
| (4) | Swansea Town | Home | W | 4-1 | |
| (5) | Chelsea | Home | L | 1-3 |
| 1965/66 | (2) | Birmingham City | Home | D | 1-1 |
| (R) | Birmingham City | Away | W | 3-2 | |
| (3) | Nottingham Forest | Away | W | 2-1 | |
| (4) | Arsenal | Away | L | 0-1 |
| 1966/67 | (2) | Coventry City | Home | L | 0-2 |
| 1967/68 | (2) | Coventry City | Home | L | 2-5 |
| 1968/69 | (1) | Shrewsbury Town | Away | W | 8-0 |
| (2) | Stoke City | Away | L | 0-4 |
| 1969/70 | (1) | Walsall | Home | W | 5-0 |
| (2) | Clifton All Whites | Away | W | 2-0 | |
| (3) | Northampton Town | Away | D | 2-2 | |
| (R) | Northampton Town | Home | W | 6-1 | |
| (4) | Stoke City | Home | D | 1-1 | |
| (R) | Stoke City | Away | L | 0-1 |
| 1970/71 | (2) | Northfield | Home | W | 7-0 |
| (3) | Aston Villa | Away | W | 2-0 | |
| (4) | Preston North End | Home | W | 5-0 | |
| (5) | West Ham United | Away | D | 1-1 | |
| (R) | West Ham United | Home | D | 2-2 | |
| (R) | West Ham United | Home | W | 1-0 | |
| (SF/1) | Arsenal | Away | L | 0-2 | |
| (SF/2) | Arsenal | Home | L | 0-1 |
| 1971/72 | (1) | Northfield | Away | W | 1-0 |
| (2) | Stoke City | Home | D | 1-1 | |
| (R) | Stoke City | Away | L | 2-3 |
| 1972/73 | (2) | Bolton Wanderers | Home | D | 0-0 |
| (R) | Bolton Wanderers | Away | L | 1-6 |
| 1973/74 | (2) | Wigan Athletic | Away | D | 0-0 |
| (R) | Wigan Athletic | Home | W | 4-3 | |
| (3) | Stoke City | Home | D | 1-1 | |
| (R) | Stoke City | Away | L | 1-2 |
| 1974/75 | (2) | Stoke City | Away | W | 3-0 |
| (3) | Tottenham Hotspur | Away | L | 1-4 |
| 1975/76 | (2) | Birmingham City | Away | D | 1-1 |
| (R) | Birmingham City | Home | W | 2-1 | |
| (3) | Fulham | Away | D | 1-1 | |
| (R) | Fulham | Home | W | 3-2 | |
| (4) | Tottenham Hotspur | Away | D | 2-2 | |
| (R) | Tottenham Hotspur | Home | W | 4-0 | |
| (5) | Queens Park Rangers | Away | W | 1-0 | |
| (SF/1) | Newcastle United | Away | W | 2-1 | |
| (SF/2) | Newcastle United | Home | W | 2-1 | |
| (F/1) | West Bromwich Albion | Home | L | 0-2 | |
| (F/2) | West Bromwich Albion | Away | L | 0-3 |
| 1976/77 | (2) | Nuneaton Borough | Home | W | 3-1 |
| (3) | Bristol Rovers | Away | W | 1-0 | |
| (4) | West Bromwich Albion | Away | L | 0-4 |
| 1977/78 | (2) | Hereford United | Away | L | 0-1 |
| 1978/79 | (2) | Coventry City | Away | D | 3-3 |
| (R) | Coventry City | Home | L | 0-1 |
| 1979/80 | (2) | Shrewsbury Town | Away | D | 0-0 |
| (R) | Shrewsbury Town | Home | D | 2-2 | |
| (R) | Shrewsbury Town | Away | L | 3-5 |
| 1980/81 | (1) | Bury | Home | D | 1-1 |
| (R) | Bury | Away | W | 2-1 | |
| (2) | Stoke City | Away | D | 2-2 | |
| (R) | Stoke City | Home | L | 3-5 |
| 1981/82 | (1) | Mansfield Town | Home | W | 3-0 |
| (2) | Lincoln City | Away | W | 3-0 | |
| (3) | Stoke City | Away | D | 1-1 | |
| (R) | Stoke City | Home | W | 4-1 | |
| (4) | Charlton Athletic | Home | W | 1-0 | |
| (5) | Queens Park Rangers | Away | D | 3-3 | |
| (R) | Queens Park Rangers | Home | W | 2-1 | |
| (SF/1) | Watford | Away | L | 1-2 | |
| (SF/2) | Watford | Home | L | 1-5 |
| 1982/83 | (2) | Leicester City | Home | L | 0-2 |
| 1983/84 | (2) | Barnsley | Home | D | 1-1 |
| (R) | Barnsley | Away | L | 1-2 |
| 1984/85 | (1) | Stoke City | Away | W | 1-0 |
| (2) | Barnsley | Away | L | 0-1 |
| 1985/86 | (2) | Coventry City | Away | L | 1-7 |
| 1986/87 | (1) | Luton Town | Away | L | 1-5 |
| 1987/88 | (1) | Hednesford Town | Home | W | 6-0 |
| (2) | Coventry City | Away | L | 2-3 |
| 1988/89 | (1) | Walsall | Away | L | 2-3 |
| 1989/90 | (1) | Northampton Town | Away | D | 0-0 |
| (R) | Northampton Town | Home | W | 3-1 | |
| (2) | Cambridge United | Away | W | 2-1 | |
| (3) | Leeds United | Home | W | 3-2 | |
| (4) | Tottenham Hotspur | Away | L | 1-4 |
| 1990/91 | (1) | Port Vale | Home | D | 2-2 |
| (R) | Port Vale | Away | W | 1-0 | |
| (2) | Walall | Home | L | 0-2 |
| 1991/92 | (1) | Nottingham Forest | Away | D | 0-0 |
| (R) | Nottingham Forest | Home | D | 0-0 | |
| (R) | Nottingham Forest | Away | W | 1-0 | |
| (2) | West Bromwich Albion | Away | L | 1-3 |
| 1992/93 | (1) | Kidderminster Harriers | Away | W | 7-2 |
| (2) | Birmingham City | Away | D | 4-4 | |
| (R) | Birmingham City | Home | W | 4-1 | |
| (3) | Sheffield United | Away | L | 3-4 |
| 1993/94 | (1) | Birmingham City | Away | L | 1-4 |
| 1994/95 | (1) | Cambridge United | Home | D | 1-1 |
| (R) | Cambridge United | Away | W | 6-2 | |
| (2) | Brentford | Home | W | 2-0 | |
| (3) | Tottenham Hotspur | Away | L | 2-4 |
| 1995/96 | (1) | Birmingham City | Home | L | 5-6 |
| 1996/97 | (1) | Welling United | Away | W | 1-0 |
| (2) | Wycombe Wanderers | Home | L | 2-3 |
| 1997/98 | (1) | Stoke City | Away | L | 0-3 |
| 1998/99 | (3) | Middlesbrough | Away | L | 1-2 |
| 1999/00 | (3) | Derby County | Away | D | 0-0 |
| (R) | Derby County | Home | L | 0-2 |
| 2000/01 | (3) | Stoke City | Away | D | 0-0 |
| (R) | Stoke City | Home | W | 2-0 | |
| (4) | York City | Home | W | 2-0 | |
| (5) | Wimbledon | Home | L | 0-3 |
| 2001/02 | (3) | Crystal Palace | Away | D | 1-1* |
* Wolves lost 4-2 on penalties
| 2002/03 | (3) | Walsall | Away | W | 4-0 |
| (4) | Charlton Athletic | Away | L | 0-1 |
| 2003/04 | (3) | Barnsley | Away | W | 3-0 |
| (4) | Rotherham United | Home | L | 0-2 |
| 2004/05 | (3) | Reading | Home | W | 1-0 |
| (4) | Barnsley | Home | W | 2-1 | |
| (5) | Manchester City | Home | W | 2-0 | |
| (6) | Derby County | Away | W | 2-1 | |
| (SF/1) | Southampton | Away | L | 0-1 | |
| (SF/2) | Southampton* | Home | W | 3-2 |
* Wolves Lost on away goals
| 2005/06 | (3) | Cheltenham Town | Away | W | 3-2 |
| (4) | Charlton Athletic | Home | L | 1-2 |
| 2006/07 | (3) | Leicester City | Away | W | 2-1 |
| (4) | Middlesbrough | Away | L | 1-2 |
| 2007/08 | (3) | Charlton Athletic | Home | L | 2-3 |
| 2008/09 | (3) | Leicester City | Away | W | 3-2 |
| (4) | Arsenal | Away | L | 1-3 |
| 2009/10 | (3) | Liverpool | Away | L | 0-2 |
| 2010/11 | (3) | Everton | Away | L | 1-2 |
| 2011/12 | (3) | West Ham United | Home | L | 2-3 |
| 2012/13 | (3) | Charlton Athletic | Home | L | 0-1 |
| 2013/14 | (1) | Burton Albion | Home | W | 5-0 |
| (2) | Peterborough United | Home | L | 1-2 |
| 2014/15 | (3) | Rotherham United | Away | W | 2-1 |
| (4) | Tottenham Hotspur | Away | L | 0-2 |
| 2015/16 | (1) | MK Dons | Home | W | 3-0 |
| (2) | Metropolitan Police | Home | W | 5-0 | |
| (3) | Reading | Home | L | 0-3 |
| 2016/17 | (3) | Swansea City | Away | L | 1-2 |